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Fine structure is due to two mechanisms: relativistic correction and spin-orbit coupling. In other words, a very small perturbation (correction) to the Bohr energies.
The equation of which is: <math>H_{fs}=\alpha\vec{S}\vec{L}</math>
By considering the relativistic version of momentum: <math>p=\frac{mv} {\sqrt{1-(\frac v {c})^2}}</math>. We can derive the relativistic equation for kinetic energy: <math>T=\sqrt{m^2c^4+p^2c^2}-mc^2</math>.
With <math>p«mc</math> (the non-relativistic limit) we get <math>T=\frac {p^2} {2m}-\frac{p^4} {8m^3c^2}</math>
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