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Please try to include the following
notation: |1/2 -1/2>
What is the big picture? Why do we do the math?
<math>\chi_+ = \begin{pmatrix} 1
0\end{pmatrix}</math>
<math>\chi_- = \begin{pmatrix} 0
1\end{pmatrix}</math>
<math>|“m”| =< l</math>
Se,p,n,q,nu = 1/2 is an intrinsic property that doesn't change. You can just say Sz,ms,m = +/- 1/2 <math>\hbar</math> ←(the <math>\hbar</math> is really supposed to be there, but it is usually left out of the notation).
S2 = <math>\frac{1}{2}(\frac{1}{2}+1)\hbar</math>2. Compare to the shallow well with only 2 states.
<math>\psi = c_1\psi_1 + c_2\psi_2</math> ⇒ <math>\begin{pmatrix} c_1
c_2\end{pmatrix}</math>, then <math>\begin{pmatrix} 1
0\end{pmatrix}</math> is <math>\psi_1</math> the ground state and <math>\begin{pmatrix} 0
1\end{pmatrix}</math> is the first excited state <math>\psi_2</math>.
When you have spin momentum it creates a magnetic dipole, <math>\psi_1</math> and <math>\psi_2</math> are degenerate states when without a magnetic field. Apply magnetic field and <math>\psi_1</math>, <math>\psi_2</math> take different energies.
Q: How do we know they are degenerate without a magnetic field?
A: <math>\psi = \psi_nlm</math> sz +/- <math>\frac{1}{2}</math>. When it decays there's emission of photon with energy equal to the difference. The spin decay +/- <math>\frac{1}{2}</math> → +/- <math>\frac{1}{2}</math> makes no difference of photon energy without a magnetic field, but with it, experiments started showing a difference. Two peaks on a plot of measurements (which collapse to one peak without a magnetic field).
We could use convention <math>\chi_+</math>x = <math>\begin{pmatrix} 1
0\end{pmatrix}</math> <math>\chi_-</math>x = <math>\begin{pmatrix} 0
1\end{pmatrix}</math> for spin up and spin down, but its confusing. If the z-component is discrete, not continuous, then it snaps into allowed spots (up or down). There can only be an even number of allowed spots, why is that?
S2,sz,sx,sy (sometimes the x and y components) like a microwave has a magnetic field that lines up hydrogen in H2O, then microwaves flip the spin over.
S2 = <math>\frac{3}{4}\hbar</math>2<math>\begin{pmatrix} 1 0
0 -1\end{pmatrix}</math> ⇒ <math>\frac{3}{4}\hbar</math>2<math>\begin{pmatrix} 1 0
0 -1\end{pmatrix}\begin{pmatrix} 1
0\end{pmatrix} = \frac{3}{4}\hbar</math>2<math>\begin{pmatrix} 1
0\end{pmatrix}</math>
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